| Red | Players | Sections | Competition |
|---|---|---|---|
| 1 | Emre Can | Group Stage | UEFA Champions League 21/22 |
| 1 | Mats Hummels | Group Stage | UEFA Champions League 21/22 |
| 1 | Julian Weigl | Group Stage | UEFA Champions League 19/20 |
| 1 | Emre Can | Round of 16 | UEFA Champions League 19/20 |
| 1 | Roman Weidenfeller | Group Stage | UEFA Champions League 13/14 |
| 1 | Matthias Sammer | Quarter-finals | UEFA Champions League 95/96 |
| 1 | Stefan Reuter | Quarter-finals | UEFA Champions League 96/97 |
| 1 | Lars Ricken | First Group Stage | UEFA Champions League 99/00 |
| 1 | Marcio Amoroso | First Group Stage | UEFA Champions League 01/02 |
UEFA Champions League 24/25 Top goal scorers