| MD | Players | Clubs | Nationality | DOB | A(D) |
|---|---|---|---|---|---|
| 25-Aug-2006 |  Lionel Messi | Barcelona | Argentina | 24-Jun-1987 | 19(62) |
| 25-Aug-2006 |  Jesus Navas | Sevilla | Spain | 21-Nov-1985 | 20(277) |
| 25-Aug-2006 | Antonio Puerta | Sevilla | Spain | 26-Nov-1984 | 21(272) |
| 25-Aug-2006 | Adriano | Sevilla | Brazil | 26-Oct-1984 | 21(303) |
| 25-Aug-2006 | Andres Iniesta | Barcelona | Spain | 11-May-1984 | 22(106) |
| 25-Aug-2006 | Dani Alves | Sevilla | Brazil | 06-May-1983 | 23(111) |
| 25-Aug-2006 | Thiago Motta | Barcelona | Italy | 28-Aug-1982 | 23(362) |
| 25-Aug-2006 | Victor Valdes | Barcelona | Spain | 14-Jan-1982 | 24(223) |
| 25-Aug-2006 | Samuel Eto'o | Barcelona | Cameroon | 10-Mar-1981 | 25(168) |
| 25-Aug-2006 | Luis Fabiano | Sevilla | Brazil | 08-Nov-1980 | 25(290) |
| 25-Aug-2006 | Ronaldinho Gaucho | Barcelona | Brazil | 21-Mar-1980 | 26(157) |
| 25-Aug-2006 | Christian Poulsen | Sevilla | Denmark | 28-Feb-1980 | 26(179) |
| 25-Aug-2006 | Enzo Maresca | Sevilla | Italy | 10-Feb-1980 | 26(197) |
| 25-Aug-2006 | Xavi | Barcelona | Spain | 25-Jan-1980 | 26(213) |
| 25-Aug-2006 | Julien Escude | Sevilla | France | 17-Aug-1979 | 27(8) |
| 25-Aug-2006 | Renato | Sevilla | Brazil | 15-May-1979 | 27(102) |
| 25-Aug-2006 | Rafael Marquez (Mex) | Barcelona | Mexico | 13-Feb-1979 | 27(193) |
| 25-Aug-2006 | Eidur Gudjohnsen | Barcelona | Iceland | 15-Sep-1978 | 27(344) |
| 25-Aug-2006 | Carles Puyol | Barcelona | Spain | 13-Apr-1978 | 28(134) |
| 25-Aug-2006 | Frederic Kanoute | Sevilla | Mali | 02-Sep-1977 | 28(357) |
| 25-Aug-2006 | Deco | Barcelona | Portugal | 27-Aug-1977 | 28(363) |
| 25-Aug-2006 | Ludovic Giuly | Barcelona | France | 10-Jul-1976 | 30(46) |
| 25-Aug-2006 | Juliano Belletti | Barcelona | Brazil | 20-Jun-1976 | 30(66) |
| 25-Aug-2006 | Silvinho | Barcelona | Brazil | 12-Apr-1974 | 32(135) |
| 25-Aug-2006 | Javi Navarro | Sevilla | Spain | 06-Feb-1974 | 32(200) |
| 25-Aug-2006 | David Castedo | Sevilla | Spain | 26-Jan-1974 | 32(211) |
| 25-Aug-2006 | Andres Palop | Sevilla | Spain | 22-Oct-1973 | 32(307) |
MD = Match date,
DOB = Date Of Birth,
A(D) = Age(Days).