| MD | Players | Clubs | Nationality | DOB | A(D) |
|---|---|---|---|---|---|
| 29-Aug-2012 |  Xavi | Barcelona | Spain | 25-Jan-1980 | 32(217) |
| 29-Aug-2012 |  Iker Casillas | Real Madrid | Spain | 20-May-1981 | 31(102) |
| 29-Aug-2012 | Xabi Alonso | Real Madrid | Spain | 25-Nov-1981 | 30(278) |
| 29-Aug-2012 | Victor Valdes | Barcelona | Spain | 14-Jan-1982 | 30(228) |
| 29-Aug-2012 | Alvaro Arbeloa | Real Madrid | Spain | 17-Jan-1983 | 29(225) |
| 29-Aug-2012 | Pepe | Real Madrid | Portugal | 26-Feb-1983 | 29(185) |
| 23-Aug-2012 | Dani Alves | Barcelona | Brazil | 06-May-1983 | 29(110) |
| 29-Aug-2012 | Andres Iniesta | Barcelona | Spain | 11-May-1984 | 28(110) |
| 29-Aug-2012 | Javier Mascherano | Barcelona | Argentina | 08-Jun-1984 | 28(82) |
| 29-Aug-2012 | Adriano | Barcelona | Brazil | 26-Oct-1984 | 27(307) |
| 29-Aug-2012 | Cristiano Ronaldo | Real Madrid | Portugal | 05-Feb-1985 | 27(205) |
| 29-Aug-2012 | Luka Modric | Real Madrid | Croatia | 09-Sep-1985 | 26(355) |
| 23-Aug-2012 | Raul Albiol | Real Madrid | Spain | 04-Sep-1985 | 26(354) |
| 29-Aug-2012 | Sergio Ramos | Real Madrid | Spain | 30-Mar-1986 | 26(153) |
| 29-Aug-2012 | Gerard Pique | Barcelona | Spain | 02-Feb-1987 | 25(209) |
| 29-Aug-2012 | Jose Callejon | Real Madrid | Spain | 11-Feb-1987 | 25(200) |
| 29-Aug-2012 | Sami Khedira | Real Madrid | Germany | 04-Apr-1987 | 25(148) |
| 23-Aug-2012 | Francesc Fabregas | Barcelona | Spain | 04-May-1987 | 25(112) |
| 29-Aug-2012 | Lionel Messi | Barcelona | Argentina | 24-Jun-1987 | 25(67) |
| 29-Aug-2012 | Pedro Rodriguez | Barcelona | Spain | 28-Jul-1987 | 25(33) |
| 29-Aug-2012 | Alex Song | Barcelona | Cameroon | 09-Sep-1987 | 24(355) |
| 29-Aug-2012 | Gonzalo Higuain | Real Madrid | Argentina | 10-Dec-1987 | 24(263) |
| 29-Aug-2012 | Karim Benzema | Real Madrid | France | 19-Dec-1987 | 24(254) |
| 29-Aug-2012 | Angel Di Maria | Real Madrid | Argentina | 14-Feb-1988 | 24(197) |
| 23-Aug-2012 | Fabio Coentrao | Real Madrid | Portugal | 11-Mar-1988 | 24(165) |
| 29-Aug-2012 | Marcelo | Real Madrid | Brazil | 12-May-1988 | 24(109) |
| 29-Aug-2012 | Sergio Busquets | Barcelona | Spain | 16-Jul-1988 | 24(44) |
| 29-Aug-2012 | Mesut Ozil | Real Madrid | Germany | 15-Oct-1988 | 23(318) |
| 29-Aug-2012 | Alexis Sanchez | Barcelona | Chile | 19-Dec-1988 | 23(253) |
| 29-Aug-2012 | Jordi Alba | Barcelona | Spain | 21-Mar-1989 | 23(161) |
| 23-Aug-2012 | Cristian Tello | Barcelona | Spain | 11-Aug-1991 | 21(13) |
MD = Match date,
DOB = Date Of Birth,
A(D) = Age(Days).