| Date | Result | OPP | FS | Home/Away |
|---|---|---|---|---|
| 13-Aug-2022 | draw |  Celta Vigo | 2-2 | away |
| 19-Aug-2022 | lose |  Rayo Vallecano | 0-2 | home |
| 28-Aug-2022 | lose |  Real Madrid | 1-3 | home |
| 10-Sep-2022 | lose |  Sevilla | 2-3 | home |
| 18-Sep-2022 | lose |  Real Sociedad | 2-1 | away |
| 02-Oct-2022 | draw |  Valencia | 2-2 | home |
| 09-Oct-2022 | draw |  Cadiz CF | 2-2 | away |
| 20-Oct-2022 | lose |  Osasuna | 1-0 | away |
| 23-Oct-2022 | draw |  Elche CF | 2-2 | home |
| 28-Oct-2022 | draw |  RCD Mallorca | 1-1 | away |
| 09-Nov-2022 | lose |  Villarreal | 0-1 | home |
| 31-Dec-2022 | draw |  Barcelona | 1-1 | away |
| 07-Jan-2023 | draw | Girona FC | 2-2 | home |
| 27-Jan-2023 | lose |  UD Almeria | 3-1 | away |
| 04-Feb-2023 | draw | Osasuna | 1-1 | home |
| 13-Feb-2023 | lose | Real Sociedad | 2-3 | home |
| 05-Mar-2023 | lose |  Real Valladolid | 2-1 | away |
| 18-Mar-2023 | lose | Celta Vigo | 1-3 | home |
| 01-Apr-2023 | lose | Girona FC | 2-1 | away |
| 08-Apr-2023 | lose |  Athletic Bilbao | 1-2 | home |
| 15-Apr-2023 | lose |  Real Betis | 3-1 | away |
| 04-May-2023 | lose | Sevilla | 3-2 | away |
| 14-May-2023 | lose | Barcelona | 2-4 | home |
| 24-May-2023 | draw |  Atletico Madrid | 3-3 | home |
| 28-May-2023 | draw | Valencia | 2-2 | away |
| 04-Jun-2023 | draw | UD Almeria | 3-3 | home |
Overall ( 0 wins,11 draw,15 lost )
Home ( 0 wins,6 draw,8 lost )
Away ( 0 wins,5 draw,7 lost )
OPP = Opposition,
FS = Final score.