| Date | Result | OPP | FS | Home/Away |
|---|---|---|---|---|
| 27-Aug-2012 | lose |  Real Valladolid | 2-0 | away |
| 02-Sep-2012 | win |  Espanyol | 3-2 | home |
| 15-Sep-2012 | lose |  Malaga | 3-1 | away |
| 23-Sep-2012 | win |  Real Sociedad | 2-1 | home |
| 30-Sep-2012 | lose |  Osasuna | 4-0 | away |
| 11-Nov-2012 | lose |  Real Madrid | 1-2 | home |
| 25-Nov-2012 | lose |  Barcelona | 0-4 | home |
| 02-Dec-2012 | draw |  Celta Vigo | 1-1 | away |
| 20-Dec-2012 | lose |  Rayo Vallecano | 3-0 | away |
| 05-Jan-2013 | win |  Athletic Bilbao | 3-1 | home |
| 13-Jan-2013 | lose |  Real Betis | 2-0 | away |
| 20-Jan-2013 | lose |  Atletico Madrid | 2-0 | away |
| 26-Jan-2013 | win | Real Valladolid | 2-1 | home |
| 02-Feb-2013 | lose | Espanyol | 3-2 | away |
| 17-Feb-2013 | draw | Real Sociedad | 1-1 | away |
| 25-Feb-2013 | lose | Osasuna | 0-2 | home |
| 17-Mar-2013 | draw |  Granada CF | 1-1 | away |
| 13-Apr-2013 | lose |  Deportivo La Coruna | 0-4 | home |
| 20-Apr-2013 | lose | Barcelona | 1-0 | away |
| 27-Apr-2013 | lose | Celta Vigo | 0-1 | home |
| 05-May-2013 | draw |  RCD Mallorca | 1-1 | away |
| 19-May-2013 | lose | Rayo Vallecano | 2-3 | home |
Overall ( 4 wins,4 draw,14 lost )
Home ( 4 wins,0 draw,6 lost )
Away ( 0 wins,4 draw,8 lost )
OPP = Opposition,
FS = Final score.