| Red | Players | Sections | Competition |
|---|---|---|---|
| 1 | Pepe | Group Stage | 2014 FIFA World Cup |
| 1 | Ricardo Costa | Last 16 | 2010 FIFA World Cup |
| 1 | Costinha | Second Round | 2006 FIFA World Cup |
| 1 | Deco | Second Round | 2006 FIFA World Cup |
| 1 | Joao Pinto | Group Stage | 2002 FIFA World Cup |
| 1 | Beto | Group Stage | 2002 FIFA World Cup |
2022 FIFA World Cup Top goal scorers