| Group E | P | W | D | L | GF | GA | GD | points |
|---|---|---|---|---|---|---|---|---|
 Bayern Munich | 6 | 6 | 0 | 0 | 22 | 3 | 19 | 18 |
 Benfica | 6 | 2 | 2 | 2 | 7 | 9 | -2 | 8 |
 Barcelona | 6 | 2 | 1 | 3 | 2 | 9 | -7 | 7 |
 Dynamo Kyiv | 6 | 0 | 1 | 5 | 1 | 11 | -10 | 1 |
Wednesday 8 December 2021 | |||||||
| Benfica | 2 | - | 0 | Dynamo Kyiv | 19:00 | STATS» | |
| Bayern Munich | 3 | - | 0 | Barcelona | 19:00 | STATS» | |
Tuesday 23 November 2021 | |||||||
| Barcelona | 0 | - | 0 | Benfica | 19:00 | STATS» | |
| Dynamo Kyiv | 1 | - | 2 | Bayern Munich | 16:45 | STATS» | |
Tuesday 2 November 2021 | |||||||
| Dynamo Kyiv | 0 | - | 1 | Barcelona | 19:00 | STATS» | |
| Bayern Munich | 5 | - | 2 | Benfica | 19:00 | STATS» | |
Wednesday 20 October 2021 | |||||||
| Benfica | 0 | - | 4 | Bayern Munich | 19:00 | STATS» | |
| Barcelona | 1 | - | 0 | Dynamo Kyiv | 16:45 | STATS» | |
Wednesday 29 September 2021 | |||||||
| Bayern Munich | 5 | - | 0 | Dynamo Kyiv | 19:00 | STATS» | |
| Benfica | 3 | - | 0 | Barcelona | 19:00 | STATS» | |
Tuesday 14 September 2021 | |||||||
| Dynamo Kyiv | 0 | - | 0 | Benfica | 19:00 | STATS» | |
| Barcelona | 0 | - | 3 | Bayern Munich | 19:00 | STATS» | |