| Group F | P | W | D | L | GF | GA | GD | points |
|---|---|---|---|---|---|---|---|---|
 Valencia | 6 | 3 | 3 | 0 | 8 | 4 | 4 | 12 |
 Bayern Munich | 6 | 2 | 3 | 1 | 7 | 6 | 1 | 9 |
 Rangers | 6 | 2 | 1 | 3 | 7 | 7 | 0 | 7 |
 PSV Eindhoven | 6 | 1 | 1 | 4 | 5 | 10 | -5 | 4 |
Wednesday 3 November 1999 | |||||||
| Valencia | 1 | - | 0 | PSV Eindhoven | 18:45 | STATS» | |
| Bayern Munich | 1 | - | 0 | Rangers | 18:45 | STATS» | |
Tuesday 26 October 1999 | |||||||
| Rangers | 1 | - | 2 | Valencia | 18:45 | STATS» | |
| PSV Eindhoven | 2 | - | 1 | Bayern Munich | 18:45 | STATS» | |
Wednesday 20 October 1999 | |||||||
| Valencia | 1 | - | 1 | Bayern Munich | 18:45 | STATS» | |
| Rangers | 4 | - | 1 | PSV Eindhoven | 18:45 | STATS» | |
Tuesday 28 September 1999 | |||||||
| Bayern Munich | 1 | - | 1 | Valencia | 18:45 | STATS» | |
| PSV Eindhoven | 0 | - | 1 | Rangers | 18:45 | STATS» | |
Tuesday 21 September 1999 | |||||||
| PSV Eindhoven | 1 | - | 1 | Valencia | 18:45 | STATS» | |
| Rangers | 1 | - | 1 | Bayern Munich | 18:45 | STATS» | |
Wednesday 15 September 1999 | |||||||
| Valencia | 2 | - | 0 | Rangers | 18:45 | STATS» | |
| Bayern Munich | 2 | - | 1 | PSV Eindhoven | 18:45 | STATS» | |