| MD | Players | Clubs | Nationality | DOB | A(D) |
|---|---|---|---|---|---|
| 11-Aug-2021 |  Raul Albiol | Villarreal | Spain | 04-Sep-1985 | 35(342) |
| 11-Aug-2021 | Etienne Capoue | Villarreal | France | 07-Nov-1988 | 32(277) |
| 11-Aug-2021 | Sergio Asenjo | Villarreal | Spain | 28-Jun-1989 | 32(44) |
| 11-Aug-2021 |  Cesar Azpilicueta | Chelsea | Spain | 28-Aug-1989 | 31(349) |
| 11-Aug-2021 | Mario Gaspar | Villarreal | Spain | 24-Nov-1990 | 30(261) |
| 11-Aug-2021 | Marcos Alonso | Chelsea | Spain | 28-Dec-1990 | 30(227) |
| 11-Aug-2021 | N'Golo Kante | Chelsea | France | 29-Mar-1991 | 30(136) |
| 11-Aug-2021 | Manu Trigueros | Villarreal | Spain | 17-Oct-1991 | 29(299) |
| 11-Aug-2021 | Aissa Mandi | Villarreal | Algeria | 22-Oct-1991 | 29(294) |
| 11-Aug-2021 | Jorginho | Chelsea | Italy | 20-Dec-1991 | 29(235) |
| 11-Aug-2021 | Edouard Mendy | Chelsea | Senegal | 01-Mar-1992 | 29(163) |
| 11-Aug-2021 | Gerard Moreno | Villarreal | Spain | 07-Apr-1992 | 29(126) |
| 11-Aug-2021 | Alberto Moreno | Villarreal | Spain | 05-Jul-1992 | 29(37) |
| 11-Aug-2021 | Antonio Rudiger | Chelsea | Germany | 03-Mar-1993 | 28(161) |
| 11-Aug-2021 | Hakim Ziyech | Chelsea | Morocco | 19-Mar-1993 | 28(145) |
| 11-Aug-2021 | Mateo Kovacic | Chelsea | Croatia | 06-May-1994 | 27(97) |
| 11-Aug-2021 | Kepa Arrizabalaga | Chelsea | Spain | 03-Oct-1994 | 26(313) |
| 11-Aug-2021 | Moises Gomez | Villarreal | Spain | 20-Oct-1994 | 26(296) |
| 11-Aug-2021 | Kurt Zouma | Chelsea | France | 27-Oct-1994 | 26(289) |
| 11-Aug-2021 | Daniel Raba | Villarreal | Spain | 01-Jan-1995 | 26(223) |
| 11-Aug-2021 | Timo Werner | Chelsea | Germany | 06-Mar-1996 | 25(158) |
| 11-Aug-2021 | Alfonso Pedraza | Villarreal | Spain | 09-Apr-1996 | 25(124) |
| 11-Aug-2021 | Andreas Christensen | Chelsea | Denmark | 10-Apr-1996 | 25(123) |
| 11-Aug-2021 | Boulaye Dia | Villarreal | Senegal | 16-Nov-1996 | 24(268) |
| 11-Aug-2021 | Pau Torres | Villarreal | Spain | 16-Jan-1997 | 24(207) |
| 11-Aug-2021 | Juan Foyth | Villarreal | Argentina | 12-Jan-1998 | 23(211) |
| 11-Aug-2021 | Pervis Estupinan | Villarreal | Ecuador | 21-Jan-1998 | 23(202) |
| 11-Aug-2021 | Mason Mount | Chelsea | England | 10-Jan-1999 | 22(214) |
| 11-Aug-2021 | Manu Morlanes | Villarreal | Spain | 12-Jan-1999 | 22(212) |
| 11-Aug-2021 | Kai Havertz | Chelsea | Germany | 11-Jun-1999 | 22(62) |
| 11-Aug-2021 | Trevoh Chalobah | Chelsea | England | 05-Jul-1999 | 22(38) |
| 11-Aug-2021 | Callum Hudson-Odoi | Chelsea | England | 07-Nov-2000 | 20(277) |
| 11-Aug-2021 | Yeremi Pino | Villarreal | Spain | 20-Oct-2002 | 18(296) |
MD = Match date,
DOB = Date Of Birth,
A(D) = Age(Days).