| 5 | Martin Keown | First Group Stage | UEFA Champions League 00/01 |
| 4 | Olivier Giroud | Group Stage | UEFA Champions League 15/16 |
| 4 | Ray Parlour | First Group Stage | UEFA Champions League 00/01 |
| 3 | Francis Coquelin | Group Stage | UEFA Champions League 16/17 |
| 3 | Granit Xhaka | Group Stage | UEFA Champions League 16/17 |
| 3 | Mikel Arteta | Group Stage | UEFA Champions League 13/14 |
| 3 | Laurent Koscielny | Group Stage | UEFA Champions League 12/13 |
| 3 | Santi Cazorla | Group Stage | UEFA Champions League 12/13 |
| 3 | Alex Song | Group Stage | UEFA Champions League 11/12 |
| 3 | Francesc Fabregas | Group Stage | UEFA Champions League 09/10 |
| 3 | Samir Nasri | Round of 16 | UEFA Champions League 08/09 |
| 3 | Patrick Vieira | Group Stage | UEFA Champions League 98/99 |
| 3 | Thierry Henry | Group Stage | UEFA Champions League 06/07 |
| 3 | Jose Antonio Reyes | Group Stage | UEFA Champions League 05/06 |
| 3 | Patrick Vieira | First Group Stage | UEFA Champions League 02/03 |
| 3 | Patrick Vieira | First Group Stage | UEFA Champions League 01/02 |
| 2 | Mesut Ozil | Group Stage | UEFA Champions League 15/16 |
| 2 | Joel Campbell | Group Stage | UEFA Champions League 15/16 |
| 2 | Nacho Monreal | Group Stage | UEFA Champions League 15/16 |
| 2 | Alexis Sanchez | Group Stage | UEFA Champions League 15/16 |
| 2 | Gabriel Paulista | Group Stage | UEFA Champions League 15/16 |
| 2 | Kai Havertz | Round of 16 | UEFA Champions League 23/24 |
| 2 | Declan Rice | Group Section | UEFA Champions League 23/24 |
| 2 | Nacho Monreal | Group Stage | UEFA Champions League 14/15 |
| 2 | Mesut Ozil | Group Stage | UEFA Champions League 14/15 |
| 2 | Mathieu Flamini | Group Stage | UEFA Champions League 14/15 |
| 2 | Aaron Ramsey | Group Stage | UEFA Champions League 13/14 |
| 2 | Tomas Rosicky | Group Stage | UEFA Champions League 13/14 |
| 2 | Thomas Vermaelen | Group Stage | UEFA Champions League 12/13 |
| 2 | Olivier Giroud | Group Stage | UEFA Champions League 12/13 |
| 2 | Mikel Arteta | Group Stage | UEFA Champions League 12/13 |
| 2 | Lukas Podolski | Group Stage | UEFA Champions League 12/13 |
| 2 | Aaron Ramsey | Group Stage | UEFA Champions League 12/13 |
| 2 | Bacary Sagna | Group Stage | UEFA Champions League 11/12 |
| 2 | Tomas Rosicky | Group Stage | UEFA Champions League 11/12 |
| 2 | Johan Djourou | Group Stage | UEFA Champions League 11/12 |
| 2 | Bacary Sagna | Group Stage | UEFA Champions League 10/11 |
| 2 | Robin van Persie | Round of 16 | UEFA Champions League 10/11 |
| 2 | Emmanuel Eboue | Group Stage | UEFA Champions League 10/11 |
| 2 | Robin van Persie | Group Stage | UEFA Champions League 09/10 |
| 2 | Abou Diaby | Round of 16 | UEFA Champions League 09/10 |
| 2 | Emmanuel Eboue | Quarter-finals | UEFA Champions League 09/10 |
| 2 | Gael Clichy | Group Stage | UEFA Champions League 09/10 |
| 2 | Alex Song | Group Stage | UEFA Champions League 08/09 |
| 2 | Abou Diaby | Group Stage | UEFA Champions League 08/09 |
| 2 | Emmanuel Eboue | Group Stage | UEFA Champions League 08/09 |
| 2 | Emmanuel Adebayor | Quarter-finals | UEFA Champions League 08/09 |
| 2 | Robin van Persie | Group Stage | UEFA Champions League 08/09 |
| 2 | Emmanuel Petit | Group Stage | UEFA Champions League 98/99 |
| 2 | Emmanuel Adebayor | Group Stage | UEFA Champions League 07/08 |
| 2 | Denilson | Group Stage | UEFA Champions League 07/08 |
| 2 | Philippe Senderos | Round of 16 | UEFA Champions League 07/08 |
| 2 | Aliaksandr Hleb | Group Stage | UEFA Champions League 07/08 |
| 2 | Gael Clichy | Group Stage | UEFA Champions League 07/08 |
| 2 | Emmanuel Eboue | Round of 16 | UEFA Champions League 07/08 |
| 2 | Aliaksandr Hleb | Group Stage | UEFA Champions League 06/07 |
| 2 | Philippe Senderos | Group Stage | UEFA Champions League 06/07 |
| 2 | Mathieu Flamini | Group Stage | UEFA Champions League 05/06 |
| 2 | Kolo Toure | Group Stage | UEFA Champions League 05/06 |
| 2 | Thierry Henry | Round of 16 | UEFA Champions League 05/06 |
