| 3 | Matheus Nunes | Group Stage | UEFA Champions League 21/22 |
| 3 | Sebastian Coates | Group Stage | UEFA Champions League 17/18 |
| 3 | Bruno Fernandes | Group Stage | UEFA Champions League 17/18 |
| 3 | William Carvalho | Group Stage | UEFA Champions League 14/15 |
| 3 | Mauricio | Group Stage | UEFA Champions League 14/15 |
| 3 | Cedric Soares | Group Stage | UEFA Champions League 14/15 |
| 3 | Liedson | Group Stage | UEFA Champions League 06/07 |
| 2 | Ricardo Esgaio | Group Stage | UEFA Champions League 22/23 |
| 2 | Manuel Ugarte | Group Stage | UEFA Champions League 22/23 |
| 2 | Hidemasa Morita | Group Stage | UEFA Champions League 22/23 |
| 2 | Matheus Reis | Group Stage | UEFA Champions League 22/23 |
| 2 | Joao Palhinha | Group Stage | UEFA Champions League 21/22 |
| 2 | Pedro Porro | Group Stage | UEFA Champions League 21/22 |
| 2 | Paulinho | Group Stage | UEFA Champions League 21/22 |
| 2 | Zouhair Feddal | Group Stage | UEFA Champions League 21/22 |
| 2 | Gelson Martins | Group Stage | UEFA Champions League 17/18 |
| 2 | Fabio Coentrao | Group Stage | UEFA Champions League 17/18 |
| 2 | Marcos Acuna | Group Stage | UEFA Champions League 17/18 |
| 2 | Marvin Zeegelaar | Group Stage | UEFA Champions League 16/17 |
| 2 | William Carvalho | Group Stage | UEFA Champions League 16/17 |
| 2 | Joel Campbell | Group Stage | UEFA Champions League 16/17 |
| 2 | Adrien Silva | Group Stage | UEFA Champions League 16/17 |
| 2 | Joao Mario | Group Stage | UEFA Champions League 14/15 |
| 2 | Tonel | Group Stage | UEFA Champions League 08/09 |
| 2 | Joao Moutinho | Group Stage | UEFA Champions League 08/09 |
| 2 | Marco Caneira | Group Stage | UEFA Champions League 08/09 |
| 2 | Beto | Group Stage | UEFA Champions League 97/98 |
| 2 | Oceano da Cruz | Group Stage | UEFA Champions League 97/98 |
| 2 | Anderson Polga | Group Stage | UEFA Champions League 07/08 |
| 2 | Custodio | Group Stage | UEFA Champions League 06/07 |
| 2 | Tonel | Group Stage | UEFA Champions League 06/07 |
| 1 | Pedro Porro | Group Stage | UEFA Champions League 22/23 |
| 1 | Goncalo Inacio | Group Stage | UEFA Champions League 22/23 |
| 1 | Nuno Santos | Group Stage | UEFA Champions League 22/23 |
| 1 | Jeremiah St. Juste | Group Stage | UEFA Champions League 22/23 |
| 1 | Sebastian Coates | Group Stage | UEFA Champions League 22/23 |
| 1 | Pedro Goncalves | Group Stage | UEFA Champions League 22/23 |
| 1 | Paulinho | Group Stage | UEFA Champions League 22/23 |
| 1 | Manuel Ugarte | Round of 16 | UEFA Champions League 21/22 |
| 1 | Tiago Tomas | Group Stage | UEFA Champions League 21/22 |
| 1 | Goncalo Inacio | Group Stage | UEFA Champions League 21/22 |
| 1 | Tabata | Group Stage | UEFA Champions League 21/22 |
| 1 | Islam Slimani | Round of 16 | UEFA Champions League 21/22 |
| 1 | Luis Neto | Group Stage | UEFA Champions League 21/22 |
| 1 | Antonio Adan | Group Stage | UEFA Champions League 21/22 |
| 1 | Daniel Braganca | Group Stage | UEFA Champions League 21/22 |
| 1 | Sebastian Coates | Group Stage | UEFA Champions League 21/22 |
| 1 | Ricardo Esgaio | Round of 16 | UEFA Champions League 21/22 |
| 1 | Rodrigo Battaglia | Group Stage | UEFA Champions League 17/18 |
| 1 | Andre Pinto | Group Stage | UEFA Champions League 17/18 |
| 1 | Seydou Doumbia | Group Stage | UEFA Champions League 17/18 |
| 1 | William Carvalho | Group Stage | UEFA Champions League 17/18 |
| 1 | Bruno Cesar | Group Stage | UEFA Champions League 17/18 |
| 1 | Alan Ruiz | Group Stage | UEFA Champions League 17/18 |
| 1 | Cristiano Piccini | Group Stage | UEFA Champions League 17/18 |
| 1 | Bas Dost | Group Stage | UEFA Champions League 17/18 |
| 1 | Elias | Group Stage | UEFA Champions League 16/17 |
| 1 | Bryan Ruiz | Group Stage | UEFA Champions League 16/17 |
| 1 | Bruno Cesar | Group Stage | UEFA Champions League 16/17 |
| 1 | Andre | Group Stage | UEFA Champions League 16/17 |
